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Quantity of sodium dichromate(VI) calculation

For partial oxidation the equation is:

Na2Cr2O7 + 3C3H7OH + 4H2SO4 Na2SO4 + Cr2(SO4)3 + 3C2H5CHO + 7H2O

The density of propan-1-ol is 0.804 g cm-3. This means that each cm3 of propan-1-ol has a mass of 0.804 g. So 1.5 cm3 has a mass of 0.804 × 1.5 = 1.2 g.

C3H7OH = 60, so we have 1.2/60 = 0.02 mols of propan-1-ol.

The above equation shows that we need a third as much sodium dichromate for oxidation

Moles of Na2Cr2O7.2H2O required = 0.02/3 = 0.0067 mol

Na2Cr2O7.2H2O = 298

Mass of sodium dichromate required = 0.0067 × 298 = 2.0 g

We have used a bit more than this (3 g), but the distillation process should ensure that insufficient time is allowed for complete oxidation.


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