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Reactions of the halates

The halates are oxy-anions which contain a halogen.

NaClO

sodium chlorate(I)

NaClO3

sodium chlorate(V)

NaClO4

sodium chlorate(VII)

They are good oxidizing agents and will oxidize, for example, iron(II) to iron(III) and iodide to iodine . Sodium chlorate(I) is found in bleach and sodium chlorate(V) is used as a weed killer.


Sodium chlorate(V) (sodium chlorate) and sodium chlorate(VII) (sodium perchlorate) are available as solids. On heating the solids thermal decomposition takes place forming oxygen gas:

2NaClO3(s) 2NaCl(s) + 3O2(g)


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