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Theoretical yield of potassium iodate

The equation for this reaction is:

6KOH(aq) + 3I2(aq) 5KI(aq) + KIO3 (aq) + 3H2O(aq)

We reacted all of the potassium hydroxide present in the solution. We need to be able to work out the number of moles from the concentration:

Number of moles of KOH = 4 ´ 10/1000 = 0.04 mol

According to the equation 6 moles of potassium hydroxide should produce 1 mole of KIO3

6KOH º KIO3 \ Number of moles of KIO3 = 0.04/6
KIO3 = 214 \ Mass of moles of KIO3 = 0.04/6 ´ 214 = 1.43 g

We are unlikely to obtain this quantity, as some of the product will still be dissolved in the water at the filtration stage.


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