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Buffer exercise 1

100 cm3 of pH 7.0 buffer needs to be made from some 0.1 mol dm-3 potassium dihydrogenphosphate (KH2PO4) solution and 0.1 M dipotassium hydrogenphosphate (K2HPO4) solution. The following equilibrium is set up:

H2PO4-(aq) HPO42-(aq) + H+(aq)

and the Ka has a value of 1.39 × 10-7 mol dm-3. Calculate the appropriate volumes of the solutions which need to be used.

Answer


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